142 FLAMMABLE LIQUIDS - AN OVERVIEW The storage of flammable liquids is regulated in the GefStoffV and BetrSichV. Regarding the storage of hazardous substances in mobile container the requirements have been included in the TRGS 510. The TRGS 510 reflects requirements in the numbers 4,5,6 and 12 as well as the annex 1 which comply with the state of the art in respect of compliance with an implementation of these requirements. The TRGS 509 deals with the storage of flammable liquids in stationary containers and in particular with mobile container filling and emptying points. The requirements of this guideline are to be considered, if in a warehouse containers are opened for withdrawal and filling. Here then takes place an „active storage“, in contrast to a „passive storage“ in which the containers are not opened. In practice, this has a considerable influence on the measures to be taken for explosion protection and zoning. According to CLP, the inflammatory fluids are classified in In addition to the TRGS 510, the GefStoffV § 11 and Annex 1 No. 1, in particular, stipulates special regulations for fire and explosion hazards which must be observed. Quantity limits: The list is purely informative and gives a simplified overview without claiming to be complete. It is not intended to classify substances or mixtures. This must be done according to the valid regulations exclusively. FP = Flash point SB = Boiling point Temporal change in the classification of flammable liquids FP = Flash point SB = Boiling point FP = Flash point SB = Boiling point PRACTICAL INFORMATION 8 Designation Category Symbol Signal word H-phrase Criteria extremely flammable Cat. 1 Danger H224 FP < 23 °C SB ≤ 35 °C easy flammable Cat. 2 Danger H225 FP < 23 °C SB ≥ 35 °C flammable Cat. 3 Attention H226 FP ≥ 23 °C up to ≤ 60 °C VO What Quantity limit Related BetrSichV Permission § 18 10.000 l extremely flammable easy flammable BlmSchG i.V.m. 4. BlmSchV § 19 Authorization ≥ 5.000 t up to <10.000 t FP < 21 °C SB > 20 °C § 10 Authorization ≥ 10.000 t FP ≤ 100 °C BlmSchG i.V.m. 12. BlmSchV § 23a also display possible § 23b Authorization ≥ 10.000 kg extremely flammable ≥ 5.000.000 kg easy flammable flammable ≥ 50.000 kg extremely flammable ≥ 50.000.000 kg easy flammable flammable VbF 31.12.2002 BetrSichV and GefStoffV from 01.01.2003 GHS from 20.01.2009 with periods of transition Designation Criteria Designation Hazard symbol R-phrase Criteria Designation Hazard symbol H-phrase Criteria AI FP < 21 °C highly flammable F+ R12 FP < 0 °C SB ≤ 35 °C extremely flammable Cat. 1, Flame Danger H224 FP < 23 °C SB ≤ 35 °C easy flammable F R11 FP < 21 °C easy flammable Cat. 2, Flame Danger H225 FP < 23°C SB > 35°C AII FP ≥ 21 °C up to ≤ 55 °C flammable without R10 FP ≥ 21°C up to ≤ 55 °C flammable Cat. 3, Flame Attention H226 FP ≥ 23 °C up to ≤ 60 °C AIII FP ≥ 55 °C up to ≤ 100 °C - - - - - - - - B FP < 21 °C, at 15 °C in Water soluble highly flammable F+ R12 FP < 0 °C SB ≤ 35 °C extremely flammable Cat. 1, Flame Danger H224 FP < 23 °C SB ≤ 35 °C easy flammable F R11 FP < 21 °C easy flammable Cat. 2, Flame Danger H225 FP < 23°C SB > 35°C - - flammable without R10 FP ≥ 21 °C up to ≤ 55 °C flammable Cat. 3, Flame Attention H226 FP ≥ 23 °C up to ≤ 60 °C
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